蚌埠市淮河南岸某高层建筑CFG桩复合地基应用探讨

以淮河南岸一级阶地某高层建筑采用CFG桩复合地基工程实例,通过利用工程地质参数复核计算、静载荷试验、沉降观测等验证资料,来探讨说明CFG桩复合地基在该区高层建筑使用的安全适用性。     

PTA装置扩产氧化母液罐挖潜——搅拌器改造

上海石化0.4 Mt/a PTA装置扩产改造中,TJ-302氧化母液罐处理量不能满足需求,需要大幅度加快循环速度,在原有设备上增设搅拌器是最经济的选择。增设搅拌器后,又出现新问题,由于循环速度加快,设备中原有的固体含量增加,必须进行再改造。经充分的分析研究以及计算,增设了罐内轴滑动轴承,从而解决了上述问题。     

Closed form solution for predicting the horizontal capacity of masonry portal frames through limit analysis and comparison with experimental test results

The paper deals with the problem of evaluating the in-plane seismic capacity of unreinforced masonry portal frame, which can be considered the basic structural element in historical buildings. In particular, the Limit Analysis approach is used to provide simplified “closed form” expressions of the horizontal collapse multiplier, also taking into account the eventual contribution of steel tie rods. Both sliding shear and shear diagonal cracking are also considered in order to take into account the shear failure modes of the pier walls.The proposed formulations have been used for performing an extensive parametric analysis, with the aim of studying the effect of both geometry and vertical/horizontal loading distributions on the portal horizontal strength. Furthermore, the influence of the steel tie-rods has been addressed in order to understand their effectiveness on the portal seismic capacity.A comparison with the results of experimental tests on full-scale portal frames is also provided in terms of in-plane collapse multiplier and failure mechanism aimed to validate the proposed “closed form” expressions.Major outcome of this study is a simple rule of thumb, which can be used for the straightforward assessment of the horizontal strength of simple masonry structures, and for verifying the results of more complex structural analyses such as the nonlinear static analysis.     

酒钢焦煤仓储系统能力的效验

酒钢公司焦化工序新建4#焦炉项目即将建成投产。4#焦炉的供料工作也迫在眉睫,为了确保4#焦炉顺利投产,保证公司焦化工序的炼焦煤正常供给,我们对现有焦煤料场的储存能力和现有设备装备的生产能力等性能进行了效验。认为用焦煤系统现有的设备、设施,来保证集团公司逐年上升的焦煤用量是无法满足生产需求的。本文简要核算了其卸供料能力。     

Inorganic mineral doped polypyrrole for hydrogen storage in alkaline medium

Cupric chloride is used as oxidant to synthesize polypyrrole doped with inorganic mineral (ImDPpy). The formation of ImDPpy was confirmed by ¹HNMR, BET, SEM, HRTEM, DSC, FTIR, Raman, XRD, UV–vis and XPS studies. The surface area calculated for ImDPpy is 36.671 m²/g. Surface area of IMDPpy is 4.671 m²/g higher than the reported value of Ppy in the literature. In DSC, ImDPpy display a peak at 88.07 °C (endothermic glass transition temperature, Tg), Tg of ImDPpy is almost identical to that of Ppy-MWCNT composite and is higher than Tg of undoped Ppy. Electrochemical analysis of ImDPpy in 0.01 M NaOH indicated the maximum charge stored in ImDPpy in the form of protons as 8090 mF/g. The maximum hydrogen storage capacity of ImDPpy is found to be 18mAh/g at an applied current density of 1 mA/cm². The mineral doped in Ppy during polymerization is identified as [Cu₂(OH)₃Cl] from XPS and Raman analysis.     

船舶水润滑尾轴承结构设计研究进展

水润滑轴承的结构优化可以有效提高轴承的承载能力、冷却散热、减振降噪和摩擦学性能。在概述船舶水润滑尾轴承的优势和存在问题的基础上,分析归纳水润滑尾轴承内衬结构、内衬的厚度和硬度、轴承间隙、长径比、内衬表面粗糙度等结构设计参数的研究进展;以轴位水润滑尾轴承、内衬多层复合水润滑尾轴承和闭式水润滑尾轴承为例,介绍近年来几种新型水润滑尾轴承的结构设计,指出闭式水润滑尾轴承在内河及沿海船舶上具有广阔的应用前景,是未来的研究重点和发展趋势;建议水润滑尾轴承的研究应从以下方面着手,一是从微纳米尺度研究轴承微观界面润滑机制,二是在考虑轴承参数间耦合作用的基础上对轴承进行多目标优化,三是进一步研究闭式水润滑尾轴承及密封装置材料、结构和辅助装置以及水润滑添加剂,四是研究船舶水润滑尾轴承的设计规范,建立一定范围内精度满足工程需要的轴承设计计算经验公式,以简化轴承设计程序。     

Low temperature heat capacity measurements of β-Si3N4 and γ-Si3N4: Determination of the equilibrium phase boundary between β-Si3N4 and γ-Si3N4

Isobaric heat capacities of β-Si₃N₄ and γ-Si₃N₄ were measured at temperatures between 1.8 and 309.9 K with a thermal relaxation method. The measured heat capacities of γ-Si₃N₄ are smaller than those of β-Si₃N₄ in this temperature range. Using these data, we determined the standard entropies of β-Si₃N₄ and γ-Si₃N₄ to be 62.30 J·mol⁻¹ K⁻¹ and 51.79 J·mol⁻¹ K⁻¹, respectively. The equilibrium phase boundary between β-Si₃N₄ and γ-Si₃N₄ was calculated using these values and thermodynamic parameters reported in previous studies. The obtained equilibrium phase transition pressure at 2000 K is 11.4 GPa. It is lower than the experimental pressures at which γ-Si₃N₄ was synthesized in previous studies. The calculated Clapeyron slope at this temperature is 0.6 MPa K⁻¹, which is consistent with those of theoretical studies.     

Potential application of metal-organic frameworks (MOFs) for hydrogen storage: Simulation by artificial intelligent techniques

Metal-organic frameworks are a new class of materials for hydrogen adsorption/storage applications. The hydrogen storage capacity of this structure is typically related to pressure, temperature, surface area, and adsorption enthalpy. Literature provides no reliable correlation for estimating the hydrogen uptake capacity of MOFs from these easy-measured variables. Therefore, this study introduces several straightforward and accurate artificial intelligence (AI) techniques to fill this gap, initially determining the appropriate topology of AI-based methods, then comparing their performances by statistical criteria, and introducing the most accurate. This study used artificial neural networks, hybrid neuro-fuzzy systems, and support vector machines as estimators. The general regression neural networks (GRNN) with a spread of 7.92 × 10⁻⁴ shows the highest correlation with the literature data and provides a relative absolute deviation of 5.34%, mean squared error of 0.059, and coefficient of determination of 0.9946.     

压缩合成食品对人体运动能力的影响

研究选取12名生理指标相对类似的试验对象,通过采用自身对照和交叉平衡的试验设计方法,针对普通膳食和以90军用干粮为例的压缩合成食品对人体运动能力的影响进行了分析,通过测定试验对象进食2组不同营养组成的食品进行运动或训练后、恢复体内的血糖浓度水平、血乳酸浓度、血乳酸清除率、心率变化、相关激素水平变化以及不同氧化变化情况评价普通膳食和压缩合成食品对人体运动能力的影响。试验结果显示,相比于普通膳食,压缩合成食品在高强度运动以及力竭运动后维持人体运动能力方面以及体能恢复方面具有明显优越性。     

Construction of CO3O4 derived ZIF/GO electrode for outstanding stability in supercapacitors devices

The growing global demand for energy supply and environmental protection has led to the use of high-efficiency energy storage devices, which supercapacitors are used as one of these devices with high storage capacity and exceptional stability. To be used for this purpose, an easy and rapid synthetically method was used to produce the CO₃O₄/GO nanocomposite, and its electrochemical performance as the electrode material in hybrid-supercapacitors was further investigated. In this nanocomposite, the CO₃O₄ crystals with less than 500 nm particle size are uniformly in contact with the wrinkled GO sheets, that their structure and morphology were investigated by surface analyzes. In addition, the functional groups, crystallographic properties, and elemental composition were investigated using the FTIR, XRD, and EDX analyzes. To confirm the supercapacitive effectiveness of the prepared samples, the electrochemical measurements (EIS, CV, and GCD) were done. The results have shown that the values of specific capacity, energy and power densities of Co₃O₄/GO hybrid nanocomposite are 234 mAh g^?1, 16.075 W h kg^?1 and 251 W kg^?1, respectively. Also, the Co₃O₄/GO has the lowest amount of resistance compared to other electrodes. Nearly constant efficiency at 104% after 1000 cycles indicates that the nanocomposite has excellent cyclic stability. The proper electrochemical efficiency of the nanocomposite corresponds to the synergistic effect on the composition.